HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium → 1-(4-Chlorobenzyl)-3,3-dimethyl-2-methoxycarbonylcyclopent-1-ene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | 1-(4-Chlorobenzylidene)-3,3-dimethyl-2-methoxycarbonylcyclopentane | HCID 54284908 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 1-(4-Chlorobenzyl)-3,3-dimethyl-2-methoxycarbonylcyclopent-1-ene | HCID 11832772 | — |
Reaction Steps
The crude 1-(4-chlorobenzylidene)-3,3-dimethyl-2-methoxycarbonylcyclopentane obtained in Example 2 was refluxed in methanol (20 ml) containing dissolved sodium (0.3 g) for 15 minutes to give 1-(4-chlorobenzyl)-3,3-dimethyl-2-methoxycarbonylcyclopent-1-ene as an oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05136081 |
| Source dataset | uspto-grants-1992_08 |
| ORD ID | ord-57048dd90c8c4e9d9c1ddbe918e293a5 |
| Source note | uspto-grants-1992_08 |