Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
(1,1'-Biphenyl)-4-carbonitrile, 4'-(hexyloxy)- → 4-(Hexyloxy)-4'-biphenylcarboxylic acid
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | (1,1'-Biphenyl)-4-carbonitrile, 4'-(hexyloxy)- | HCID 162465 | — |
| 반응물 | 4'-(Octyloxy)-[1,1'-biphenyl]-4-carboxylic acid | HCID 2802556 | — |
| 생성물 | 4-(Hexyloxy)-4'-biphenylcarboxylic acid | HCID 3563820 | — |
반응 단계
In the synthesis of 4'-octyloxybiphenyl-4-carboxylic acid of Example 12, the same hydrolysis as in Example 12 was repeated except hat 4'-hexyloxy-4-cyanobiphenyl was used instead of 4'-octyloxy-4-cyanobiphenyl to obtain 4'-hexyloxybiphenyl-4-carboxylic acid. This 4'-hexyloxybiphenyl-carboxylic acid was condensed with (+)-4-(2-methylnonanoyl) phenol in the same manner as in the synthesis of 4-(2-metylnonanoyl) phenyl, 4'-octyloxybiphenyl-4-carboxylic acid ester of Example 13 to synthesize 4-(2-methylnonanoyl) phenyl, 4'-hexyloxybiphenyl-4-carboxylic acid ester having the aforementioned physical and chemical properties.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05137653 |
| 출처 데이터셋 | uspto-grants-1992_08 |
| ORD ID | ord-40bac2e1e4b6436c9ea7570277a44b0d |
| 출처 메모 | uspto-grants-1992_08 |