Ethanol → HCID 19764854, compound

HRID 846682Notes

Reaction equation

HRID 846682 reaction equation
S([O-])(O[O-])(=O)=[O:2].[K+].[K+].[CH:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:12]=[CH:11][C:10]=1[S:19][C:20]1[CH:25]=[CH:24][CH:23]=[C:22]([Br:26])[CH:21]=1.C(O)C.[OH2:30]>>[CH:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[CH:12]=[CH:11][C:10]=1[S:19]([C:20]1[CH:25]=[CH:24][CH:23]=[C:22]([Br:26])[CH:21]=1)(=[O:2])=[O:30]

Participants

5

Reactant 4

HCID 702EthanolHCID 962WaterHCID 10313463Potassium peroxymonosulphateHCID 19764842HCID 19764842, compound

Product 1

HCID 19764854HCID 19764854, compoundYield 82%

Conditions

Temperature
0 °C

Procedure

A solution of potassium peroxymonosulphate (17.7 g) in water (30 ml) was added to a mixture of 3-bromophenyl 2-naphthyl sulphide (3 g) and ethanol (30 ml) which had been cooled to 0° C. in an ice-bath. The mixture was stirred at ambient temperature for 18 hours and at 60° C. for 5 hours. The mixture was cooled to ambient temperature and partitioned between chloroform and water. The organic phase was dried (MgSO4) and evaporated to give 3-bromophenyl 2-naphthyl sulphone (2.7 g, 82%) as a solid which was used without further purification.

Workup

  1. temperatureThe mixture was cooled to ambient temperature
  2. custompartitioned between chloroform and water
  3. dry with materialThe organic phase was dried (MgSO4)
  4. customevaporated

Sources & evidence

ORD record
ord-6d64755f2000405a8e103af310aea8e7
Source dataset
uspto-grants-1992_08
Patent number
US05137913

Reaction notes

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