HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,5-Hexadien-3-ol → HCID 12525557, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,5-Hexadien-3-ol | HCID 79122 | — |
| Reactant | 4,7-Octadienoic acid, ethyl ester | HCID 5352798 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Product | HCID 12525557 | HCID 12525557 | 92% |
Reaction Steps
trans-4,7-Octadienol (bp 100°-102° C./20 mm) was prepared in 92% yield by lithium aluminum hydride reduction of ethyl trans-4,7-octadienoate, which was prepared in 87% yield via the Claisen orthoester rearrangement of 1,5-hexadien-3-ol by the method of Johnson et al., J. Am. Chem. Soc., 92, 741 (1970).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04293674 |
| Source dataset | uspto-grants-1981_10 |
| ORD ID | ord-5fbad5f337ea45f09f9ac5d3d611582e |
| Source note | uspto-grants-1981_10 |