HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Carbonate → 4,7,7-Trimethylbicyclo[4.1.0]hept-4-en-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | Nitrosyl chloride | HCID 17601 | — |
| Reactant | 3-Carene | HCID 26049 | — |
| Reactant | HCID 571772 | HCID 571772 | — |
| Reactant | Sodium Bisulfite | HCID 23665763 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 4,7,7-Trimethylbicyclo[4.1.0]hept-4-en-3-one | HCID 12652913 | — |
Reaction Steps
The starting material 2-caren-4-one can be produced from commercially available, optically pure (+)-3-carene. The (+)-3-carene is treated with nitrosyl chloride followed by the addition of powdered sodium carbonate. The resulting 2-caren-4-one oxime is then treated with sodium bisulfite in aqueous ethanol to yield 2-caren-4-one, the desired starting product for the inventive process.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04296038 |
| Source dataset | uspto-grants-1981_10 |
| ORD ID | ord-31bd34f315bc43ddb229dd3ac6dd9fc2 |
| Source note | uspto-grants-1981_10 |