HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 86738059, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Aluminium lithium hydride | HCID 21226445 | — |
| Reactant | HCID 86738060 | HCID 86738060 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | HCID 86738059 | HCID 86738059 | 78% |
Reaction Steps
To a solution of ethyl trans, trans, trans-2,4,7-undecatrienoate (4.7 g) in dry ether (200 ml) was added with stirring lithium aluminum hydride (1 g) under ice-cooling little by little. The mixture was stirred for an hour at the same temperature. To the resultant mixture was added ether containing water to give insoluble materials, which were removed by filtration. The organic layer was washed with water, dried over magnesium sulfate and concentrated under reduced pressure to give colorless oily trans, trans, trans-2,4,7-undecatrien-1-ol (3.4 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04297096 |
| Source dataset | uspto-grants-1981_10 |
| ORD ID | ord-e990883f9f944e07bef2c9125d8d1b2c |
| Source note | uspto-grants-1981_10 |