4-Pentenoic acid → 1-Cyclohexyl-10,10-dimethyl-1,11-diaminoundecane

HRID 848811Notes

Reaction equation

HRID 848811 reaction equation
[C:1]1([CH:7]([NH2:21])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([CH3:20])([CH3:19])[CH2:17][NH2:18])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C=CCCC(O)=O>[Ru].C>[CH:1]1([CH:7]([NH2:21])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][C:16]([CH3:19])([CH3:20])[CH2:17][NH2:18])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 611384-Pentenoic acidHCID 204361271-Phenyl-10,10-dimethyl-1,11-diaminoundecane

Product 1

HCID 204361331-Cyclohexyl-10,10-dimethyl-1,11-diaminoundecane

Reagents, catalysts & solvents 1

HCID 16218582Ruthenium carbonCatalyst

Procedure

Hydrogenation of 1-phenyl-10,10-dimethyl-1,11-diaminoundecane in the presence of a ruthenium/charcoal catalyst; b.p. 147° C./4 Pa; nD20 =1.4805.

Sources & evidence

ORD record
ord-183f05dde9cb4ab89ce96bae54de3c2e
Source dataset
uspto-grants-1981_10
Patent number
US04297480

Reaction notes

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