1-Dodecene → HCID 20564935, Verbindung

HRID 848820Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 848820
[CH2:1]([SiH:7]([Cl:9])[Cl:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH2:10]=[CH:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21]>C(O)(C)C>[CH2:1]([Si:7]([CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH3:10])([Cl:9])[Cl:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Komponenten

4

Edukt 2

HCID 81831-DodeceneHCID 92038703Dichloro(hexyl)silane

Produkt 1

HCID 20564935HCID 20564935, Verbindung

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3776IsopropanolLösungsmittel

Reaktionsbedingungen

Temperatur
50 °C

Versuchsvorschrift

The above-mentioned n-hexyldichlorosilane in an amount of 3.33 g (18 millimol), 3.36 g (20 millimol) of 1-dodecene and as a catalyst a solution of H2PtCl6 ·6H2O in isopropanol (0.05 mol % relative to dichlorosilane) were charged in a flask equipped with a cooler and the mixture was reacted with stirring in an oil bath at 50° C. for 15 hours. After reaction, reaction solution was distilled to obtain n-hexyldodecyldichlorosilane. The infrared spectrum of this compound is shown in FIG. 2. The absorption of Si--H band at 2213 cm-1 vanished. The NMR spectra of this compound is shown in FIG. 6. The formula (n--C6H13)(n--C12H25)SiCl2 for this compound was confirmed.

Aufarbeitung

  1. customequipped with a cooler
  2. customthe mixture was reacted
  3. customAfter reaction, reaction solution
  4. distillationwas distilled

Quellen und Nachweise

ORD-Eintrag
ord-b3a8d64ab1474d78a456287cf6cd4afc
Quelldatensatz
uspto-grants-1981_10
Patentnummer
US04297499

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