化工社化工社 化学情報印刷レポート · 研究参考用
1-Hexene → Silane, dichlorodihexyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Hexene | HCID 11597 | — |
| 反応物 | Dichlorosilane | HCID 61330 | — |
| 触媒 | Chloroplatinic acid | HCID 61859 | — |
| 生成物 | Silane, dichlorodihexyl- | HCID 87510 | — |
| 生成物 | Dichloro(hexyl)silane | HCID 92038703 | — |
反応手順
Dichlorosilane in an amount of 83.5 g (0.827 mol), 88.6 g of 1-hexene (1.08 mol) and 0.05 mol % of chloroplatinic acid (relative to dichlorosilane) were charged in a stainless steel reactor and sealed and subjected to reaction in a bath at a temperature of 50° C. for 5 hours. After reaction, the seal of the reactor was broken and the reacted liquid was discharged, and by vacuum distillation, n-hexyldichlorosilane was obtained with a yield of 18% and di-n-hexyldichlorosilane with a yield of 72%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04297499 |
| 出典データセット | uspto-grants-1981_10 |
| ORD ID | ord-60d939a4befd475d8458e8f2b1973f22 |
| 出典メモ | uspto-grants-1981_10 |