HuagongsheHuagongshe Chemistry Print Report · For research reference only
Gadolinium → Aluminum isopropoxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Gadolinium | HCID 23982 | — |
| Reactant | Yttrium | HCID 23993 | — |
| Reactant | Acetylacetone | HCID 31261 | — |
| Reactant | Aluminum | HCID 5359268 | — |
| Reactant | Gallium | HCID 5360835 | — |
| Solvent | Ethylene Glycol | HCID 174 | — |
| Solvent | 2-Methoxyethanol | HCID 8019 | — |
| Solvent | 1-Methoxyethanol | HCID 3015637 | — |
| Product | Aluminum isopropoxide | HCID 11143 | — |
| Product | Yttrium(iii) isopropoxide | HCID 11550724 | — |
| Product | Gadolinium (III) isopropoxide | HCID 15047187 | — |
| Product | Gallium (III) isopropoxide | HCID 22253272 | — |
Reaction Steps
Sol-gel libraries were deposited on silicon wafer substrates. Stock solutions of yttrium isopropoxide, aluminum isopropoxide, gadolinium isopropoxide and gallium isopropoxide were prepared in 2-methoxyethanol (0.25 M) refluxing under Argon for 8 hours. To each of the four stock solutions of yttrium, gadolinium, aluminum and gallium in methoxyethanol (0.25 M), 1 equivalent of 2,4-pentandione was added with stirring, followed by the addition of anhydrous ethylene glycol (15% v/v). The yttrium and gadolinium solutions contained Ce(NO)3.6H2O at 1.0 mol % as the dopant source.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06013199 |
| Source dataset | uspto-grants-2000_01 |
| ORD ID | ord-724c5c93a2274e7bba9178077f8adbb3 |
| Source note | uspto-grants-2000_01 |