HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → N'-t-butyl-N-(thiobenzoyl)-N'-(3-toluoyl)hydrazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | 3-Methylbenzoyl chloride | HCID 74375 | — |
| Reactant | N'-t-butyl-N-(thiobenzoyl)hydrazine | HCID 19367775 | — |
| Catalyst | Sodium Hydroxide | HCID 14798 | — |
| Solvent | Water | HCID 962 | — |
| Product | N'-t-butyl-N-(thiobenzoyl)-N'-(3-toluoyl)hydrazine | HCID 15294606 | — |
Reaction Steps
N't-butyl-N-(thiobenzoyl)hydrazine (ca. 1 g), m-toluoyl chloride (approx. 0.7 g) and 50% aqueous sodium hydroxide (6 drops) were mixed in 1 ml water and 10 ml toluene at 23° C. After stirring for 3 hours, ether-hexane was added and the product was isolated by filtration (0.25 g). m.p. 165-168° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06013836 |
| Source dataset | uspto-grants-2000_01 |
| ORD ID | ord-08cea03020154fc9b78df106578ce5b9 |
| Source note | uspto-grants-2000_01 |