HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → HCID 178439464, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2,2,2-Trichloroethanimidamide | HCID 35608 | — |
| Reactant | Ethyl 3-oxohexanoate | HCID 238498 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 178439464 | HCID 178439464 | 11% |
Reaction Steps
A mixture of 15.0 g (0.09 mole) trichloroacetamidine, 12.6 g (0.09 mole) potassium carbonate, 14.6 g (0.09 mole) ethyl butyrylacetate and 300 ml water was stirred overnight. The aqueous solution was decanted from the oil that formed and acidified with hydrochloric acid. The precipitate that formed was filtered, washed, and dried to give 2.6 g (11% yield). An analytical sample that was recrystallized from ligroin had mp 107°-110° C. The structure was confirmed via infrared and elemental analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04382087 |
| Source dataset | uspto-grants-1983_05 |
| ORD ID | ord-22be3c988d1a44b8af0a9cf98ff0b455 |
| Source note | uspto-grants-1983_05 |