HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzotrichloride → Propanoyl chloride, 3-bromo-2,2,3,3-tetrafluoro-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzotrichloride | HCID 7367 | — |
| Reactant | 3-Bromo-2,2,3,3-tetrafluoropropanoic acid | HCID 13328911 | — |
| Product | Propanoyl chloride, 3-bromo-2,2,3,3-tetrafluoro- | HCID 10490449 | 71% |
Reaction Steps
A mixture of 375.9 g (1.67 mol) of 3-bromotetrafluoropropionic acid, 10 g of ferric chloride, and 488.7 g (2.50 mol) of benzotrichloride was refluxed for 1.5 h, then crude product was removed, bp about 60°. Redistillation gave 287.9 g (71%) of 3-bromotetrafluoropropionyl chloride, bp 67°-68°. IR (CCl4): 5.53 (C=O). ##STR44##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04384128 |
| Source dataset | uspto-grants-1983_05 |
| ORD ID | ord-ba4a6b596f3340188c2cbfdbfd52bfa3 |
| Source note | uspto-grants-1983_05 |