HuagongsheHuagongshe Chemistry Print Report · For research reference only
O-Methylhydroxylamine → Methyl 2-(methoxycarbamoylcyclopent-1-yloxyimino)2-(fur-2-yl)acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | O-Methylhydroxylamine | HCID 4113 | — |
| Reactant | Bromoform | HCID 5558 | — |
| Reactant | 1-[(Z)-[1-(furan-2-yl)-2-methoxy-2-oxoethylidene]amino]oxycyclopentane-1-carboxylic acid | HCID 88736760 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | Methyl 2-(methoxycarbamoylcyclopent-1-yloxyimino)2-(fur-2-yl)acetate | HCID 54496876 | 75% |
Reaction Steps
This compound was prepared from methyl Z-2-(carboxycyclopent-1-yloxyimino)-2-(fur-2-yl)acetate and methoxyamine as described in Preparation 7(c) νmax (CHBr3) 3400, 3350 (--NH--), 1740 (--CO2R), 1686 cm-1 (--CONH--), τ(DMSO d6), 6.4 (--OMe), --0.88 (--CONHO), 7.7-8.7 (cylopentyl), 2.1, 3.1, 3.3 (furyl), 6.1 (--CO2Me). Yield 75%
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04385177 |
| Source dataset | uspto-grants-1983_05 |
| ORD ID | ord-eb155584ad3c40b09446c649310d78fb |
| Source note | uspto-grants-1983_05 |