HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Phenyl chloroacetohydroxamate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Chloroacetyl chloride | HCID 6577 | — |
| Reactant | O-Phenylhydroxylamine hydrochloride | HCID 6365179 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | Phenyl chloroacetohydroxamate | HCID 12774348 | 67% |
Reaction Steps
This compound was prepared from phenoxyamine hydrochloride and chloroacetyl chloride by the method described in Preparation 1, m.p. 126°-128° (decomp.), λmax (EtOH) 266.5 nm (ε15,400), νmax (Nujol) 3340, 3260, 3140 (--NH--), 1720, 1710, 1690 cm-1 (--CONH--), τ(DMSO d6) 5.79 (ClCH2CO--), -2.2 (--NH--), 2.3-3.2 (phenyl). Yield 67%
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04385177 |
| Source dataset | uspto-grants-1983_05 |
| ORD ID | ord-7ae7e2ec923a428d92cfb66263790ad0 |
| Source note | uspto-grants-1983_05 |