Bromoform → HCID 88738206, compound

HRID 851565Notes

Reaction equation

HRID 851565 reaction equation
Cl[CH2:2][C:3]([NH:5][O:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)=[O:4].[O:13]1[CH:17]=[CH:16][CH:15]=[C:14]1/[C:18](=[N:22]/[OH:23])/[C:19]([OH:21])=[O:20].C(Br)(Br)Br>CS(C)=O>[O:13]1[CH:17]=[CH:16][CH:15]=[C:14]1/[C:18](=[N:22]/[O:23][CH2:2][C:3](=[O:4])[NH:5][O:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)/[C:19]([OH:21])=[O:20]

Participants

5

Reactant 3

HCID 5558BromoformHCID 12774348Phenyl chloroacetohydroxamateHCID 14556124HCID 14556124, compound

Product 1

HCID 88738206HCID 88738206, compoundYield 50%

Reagents, catalysts & solvents 1

HCID 679Dimethyl SulfoxideSolvent

Procedure

This compound was prepared as described in Preparation 4 from phenyl chloroacetohydroxamate and Z-2-(fur-2-yl)-2-hydroxyiminoacetic acid. νmax (CHBr3) 3350 (NH), 3700-2100 (bonded OH), 1754, 1725 (--CO2H), 1705, 1680 cm-1 (--CONH--), τ(DMSO d6) 2.05, 3.11, 3.29 (furyl), 5.3 (--OCH2CO--), 2.4-3.1 (phenyl). Yield 50%.

Workup

  1. customThis compound was prepared

Sources & evidence

ORD record
ord-b8856d62ca654ab1a8f8862834269ce1
Source dataset
uspto-grants-1983_05
Patent number
US04385177

Reaction notes

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