Triethyl phosphite → HCID 13077902, compound

HRID 851703Notes

Reaction equation

HRID 851703 reaction equation
C([O:3][P:4]([O:8][CH2:9][CH3:10])[O:5][CH2:6][CH3:7])C.Cl[C:12]([O:14][C:15]1[CH:20]=[CH:19][C:18]([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[CH:17][CH:16]=1)=[O:13]>>[CH2:24]([O:23][C:21]([C:18]1[CH:19]=[CH:20][C:15]([O:14][C:12]([P:4](=[O:3])([O:5][CH2:6][CH3:7])[O:8][CH2:9][CH3:10])=[O:13])=[CH:16][CH:17]=1)=[O:22])[CH3:25]

Participants

3

Reactant 2

HCID 31215Triethyl phosphiteHCID 13077891HCID 13077891, compound

Product 1

HCID 13077902HCID 13077902, compound

Procedure

From 21.6 g (0.13 mole) of triethylphosphite and 22.8 g (0.10 mole) of 4-ethoxycarbonylphenyl chloroformate. (120° C., 2 hours). Yield 26.1 g (88%). Bp0.01 190°-2° C. nD25 1.4890.

Workup

  1. custom(120° C., 2 hours)
  2. customBp0.01 190°-2° C.

Sources & evidence

ORD record
ord-a9a26f2571ee44fd97cf4826f4fc6f6e
Source dataset
uspto-grants-1983_05
Patent number
US04386081

Reaction notes

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