Water → N,N'-Bis(salicylidene)ethylenediamine

HRID 853180Notes

Reaction equation

HRID 853180 reaction equation
[CH:1]1[CH:20]=[CH:19][C:17](=[O:18])/[C:3](=[CH:4]\[NH:5][CH2:6][CH2:7][NH:8]/[CH:9]=[C:10]2\[C:11]([CH:13]=[CH:14][CH:15]=[CH:16]\2)=[O:12])/[CH:2]=1.O>C(O)(=O)C>[CH:4](=[N:5][CH2:6][CH2:7][N:8]=[CH:9][C:10]1[C:11](=[CH:13][CH:14]=[CH:15][CH:16]=1)[OH:12])[C:3]1[C:17](=[CH:19][CH:20]=[CH:1][CH:2]=1)[OH:18]

Participants

4

Reactant 2

HCID 962WaterHCID 178515944HCID 178515944, compound

Product 1

HCID 26518N,N'-Bis(salicylidene)ethylenediamine

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

Approximately 1 mmol of SALEN ligand dissolved in acetic acid solution was loaded into each reactor tube of the Multiclave™, and 5 ml of 4:1 (weight ratio) water/EO was added at 100° C. The results are shown in Table 3.

Workup

  1. additionwas added at 100° C

Sources & evidence

ORD record
ord-ac1cf7fc8c7c4e069ddb58ebfa1b2764
Source dataset
uspto-grants-2007_08
Patent number
US07253325B2

Reaction notes

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