Aluminium lithium hydride → HCID 22935668, compound

HRID 853744Notes

Reaction equation

HRID 853744 reaction equation
[CH3:1][CH:2]1[CH2:6][CH2:5][C:4]2([CH2:11][CH:10]([CH3:12])[CH:9]=[C:8]([CH3:13])[CH2:7]2)[C:3]1=[O:14].[H-].[H-].[H-].[H-].[Li+].[Al+3]>>[CH3:1][CH:2]1[CH2:6][CH2:5][C:4]2([CH2:11][CH:10]([CH3:12])[CH:9]=[C:8]([CH3:13])[CH2:7]2)[CH:3]1[OH:14]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 22935663HCID 22935663, compound

Product 1

HCID 22935668HCID 22935668, compoundYield 87%

Procedure

A mixture of 2,6,8 and 2,7,9-trimethylspiro[4,5]dec-7-en-1-one was reduced with LiAlH4 according to the general procedure (example 2, procedure 3) to give the title product in 87% yield as a mixture of isomers. The crude product was purified by bulb-to-bulb distillation (B.p.=82° C./0.02 mbar).

Sources & evidence

ORD record
ord-5a7ea42984444f0b99fcca134e1a8452
Source dataset
uspto-grants-2007_08
Patent number
US07256170B2

Reaction notes

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