HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Gamma-Butyrolactone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Maleic Anhydride | HCID 7923 | — |
| Solvent | 1-Propanol | HCID 1031 | — |
| Product | Gamma-Butyrolactone | HCID 7302 | — |
| Product | 1,4-Butanediol | HCID 8064 | — |
Reaction Steps
In the case when the C4+ hydrogenation feedstock is the crude maleic anhydride stream, then the light impurities are also hydrogenated in the hydrogenation step and result in light hydrogenation products including ethanol and propanol, which can be removed from the hydrogenation product as an overhead product by distillation. Heavy impurities and heavy impurity hydrogenation products can be separated by conventional distillation techniques as a bottom product from the crude hydrogenation product. Maleic anhydride derivatives, such as maleic acid and fumaric acid, are hydrogenated to form a corresponding additional amount of butane-1,4-diol, γ-butyrolactone, and tetrahydrofuran.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | USRE039794E1 |
| Source dataset | uspto-grants-2007_08 |
| ORD ID | ord-a694ec6619a74f43bd367e40614989c6 |
| Source note | uspto-grants-2007_08 |