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HRID854821

反应详情

EQUATION

反应方程式

HRID 854821 的结构方程式

REACTANTS

反应物

2
结构：O[C@H](c1ccccc1)[C@H](O)c1ccccc1
HCID853019

(R,R)-(+)-Hydrobenzoin

C14H14O2

结构：CS(=O)(=O)c1ccc([C@@H](C[C@@H]2CCC(=O)C2)C(=O)Nc2cnccn2)cc1Cl
HCID58697917

未命名化合物

PRODUCTS

生成物

1
结构：CS(=O)(=O)c1ccc([C@@H](C[C@H]2CCC(=O)C2)C(=O)Nc2cnccn2)cc1Cl
HCID10432339

Piragliatin

C19H20ClN3O4S

PROCEDURE

实验过程

2(R)-(3-Chloro-4-methanesulfonyl-phenyl)-3-((R)-3-oxo-cyclopentyl)-N-pyrazin-2-yl-propionamide was prepared in a similar manner as 2(R)-(3-chloro-4-methanesulfonyl-phenyl)-3-((S)-3-oxo-cyclopentyl)-N-pyrazin-2-yl-propionamide (Example 47) starting with (R,R)-hydrobenzoin (Wang, Z.-M.; Sharpless, K. B. J. Org. Chem. 1994, 59, 8302).