HRID856866

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Mg+2]

HCID25212

Magnesium nitrate

MgN2O6

结构：CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Na+].[Na+]

HCID86587835

未命名化合物

PRODUCTS

生成物

结构：CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.CCc1c(CP(=O)([O-])[O-])cc(C(C)(C)C)c(O)c1C(C)(C)C.[Mg+2].[Mg+2]

HCID86760305

未命名化合物

PROCEDURE

实验过程

ml aqueous solution of 192 mg (0.75 mmol) magnesium nitrate.6H2O was added dropwise to 4 ml aqueous solution of 500 mg (1.4 mmol) sodium (o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate) (phosphorus compound C described above) at room temperature under stirring. After the mixture was stirred for 1 hour, the precipitates were collected by filtration, washed with water and dried to give magnesium bis(o-ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate), 359 mg (74%).

WORKUP

后处理

stirringAfter the mixture was stirred for 1 hour
filtrationthe precipitates were collected by filtration
washwashed with water
customdried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-35468e7a7df84ebd9632a64bdaf79801
来源数据集: uspto-grants-2006_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07144614B2
来源说明: uspto-grants-2006_12

反应 SMILES

[N+]([O-])([O-])=O.[Mg+2:5].[N+]([O-])([O-])=O.[CH2:10]([C:12]1[C:22]([C:23]([CH3:26])([CH3:25])[CH3:24])=[C:21]([OH:27])[C:20]([C:28]([CH3:31])([CH3:30])[CH3:29])=[CH:19][C:13]=1[CH2:14][P:15](=[O:18])([O-:17])[O-:16])[CH3:11].[Na+].[Na+]>>[CH2:10]([C:12]1[C:22]([C:23]([CH3:25])([CH3:24])[CH3:26])=[C:21]([OH:27])[C:20]([C:28]([CH3:29])([CH3:31])[CH3:30])=[CH:19][C:13]=1[CH2:14][P:15](=[O:16])([O-:18])[O-:17])[CH3:11].[CH2:10]([C:12]1[C:22]([C:23]([CH3:25])([CH3:24])[CH3:26])=[C:21]([OH:27])[C:20]([C:28]([CH3:29])([CH3:31])[CH3:30])=[CH:19][C:13]=1[CH2:14][P:15](=[O:16])([O-:18])[O-:17])[CH3:11].[Mg+2:5].[Mg+2:5]