Monoperoxyphthalic Acid Magnesium Salt → HCID 90708541, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of the sulfide of Step 12 (270 mg, 0.6 mmol) in 30 ml of CH2Cl2/MeOH (10:1) mixture at 0° C. was added MMPP (312 mg, 0.6 mmol). The reaction mixture was stirred at 0° C. for 30 minutes and then quenched with saturated aqueous NaHCO3 and extracted with EtOAc. The combined organic layers were dried over Na2SO4 and concentrated. The residue was purified by silica gel chromatography eluted with 70% EtOAc in Hexanes to provide 210 mg as a white solid.

Provenance & Evidence