HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrylic Acid → t-Butyl acrylate acrylic acid 3-hydroxypropyl methacrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrylic Acid | HCID 6581 | — |
| Reactant | Propylene glycol methyl ether acetate | HCID 7946 | — |
| Reactant | tert-Butyl acrylate | HCID 15458 | — |
| Reactant | 3-Hydroxypropyl methacrylate | HCID 17694 | — |
| Catalyst | Azobisisobutyronitrile | HCID 6547 | — |
| Product | t-Butyl acrylate acrylic acid 3-hydroxypropyl methacrylate | HCID 86601184 | 118.6% |
Reaction Steps
10 g of t-butylacrylate, 4 g of acrylic acid, 6 g of 3-hydroxypropyl methacrylate and 0.4 g of AIBN were added to 200 g of PGMEA, and were then polymerized at 60° C. for 8 hours. After completion of the polymerization, the mixture was precipitated in ether, filtered, and dried in vacuo to yield 17 g of t-butyl acrylate-acrylic acid-3-hydroxypropyl methacrylate copolymer, as a white solid, represented by Formula 2 below:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07147994B2 |
| Source dataset | uspto-grants-2006_12 |
| ORD ID | ord-eb8c73245c1e4136871d0a3dd29432be |
| Source note | uspto-grants-2006_12 |