HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 857839Generated: October 30, 2026
Potassium Carbonate → 2-Vinyl-6-methoxynaphthalene
https://huagongshe.com/reaction/857839
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 2-Bromo-6-methoxynaphthalene | HCID 78786 | — |
| Reactant | Bis(adamantan-1-yl)(butyl)phosphane | HCID 11371790 | — |
| Catalyst | palladium(II) acetate | HCID 167845 | — |
| Solvent | N-methyl-2-pyrrolidone | HCID 13387 | — |
| Product | 2-Vinyl-6-methoxynaphthalene | HCID 603535 | 92% |
Reaction Steps
50 mmol of 6-methoxy-2-bromonaphthalene and 60 mmol of potassium carbonate are dissolved in 40 ml of NMP, and 0.001 mol % of Pd(OAc)2 and 0.004 mol % of butyldiadamantyl-phosphine are added. The mixture is placed under an ethylene pressure of 20 bar and stirred at 130° C. until conversion is complete. After filtration of the insoluble constituents, washing with alkaline solution and distillation, 92% of 6-methoxy-2-vinylnaphthalene is obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US07148176B2 |
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| Source dataset | uspto-grants-2006_12 |
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| ORD ID | ord-d3638d5943ea41d8a330bbc21ef989fc |
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| Source note | uspto-grants-2006_12 |
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