Chloromethyl Methyl Ether → Benzene, 1,3-dibromo-2-(methoxymethoxy)-

HRID 858268Notes

Reaction equation

HRID 858268 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Br:8])[C:3]=1[OH:9].[CH3:10][O:11][CH2:12]Cl>>[Br:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Br:8])[C:3]=1[O:9][CH2:10][O:11][CH3:12]

Participants

3

Reactant 2

HCID 7864Chloromethyl Methyl EtherHCID 118472,6-Dibromophenol

Product 1

HCID 10661582Benzene, 1,3-dibromo-2-(methoxymethoxy)-Yield 100%

Procedure

In a manner similar to that of Example 7(a), by reaction of 19.16 g (76.1 mmol) of 2,6-dibromophenol with 7.35 g (91.3 mmol) of chloromethyl methyl ether, 22.50 g (100%) of the expected product are obtained in the form of a colourless oil.

Sources & evidence

ORD record
ord-b07d90f9e9554cefa19424f21200d990
Source dataset
uspto-grants-2006_12
Patent number
US07148245B2

Reaction notes

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