HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → 2-Hydroxyethyl 5-norbornene-2-carboxylate t-butyl 5-norbornene-2-carboxylate 5-norbornene 2-carboxylic acid maleic anhydride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | Maleic Anhydride | HCID 7923 | — |
| Reactant | 5-Norbornene-2-carboxylic acid | HCID 78949 | — |
| Reactant | 2-Hydroxyethyl bicyclo[2.2.1]hept-5-ene-2-carboxylate | HCID 12033823 | — |
| Reactant | Bicyclo[2.2.1]hept-5-ene-2-carboxylic acid, 1,1-dimethylethyl ester | HCID 15607334 | — |
| Solvent | Toluene | HCID 1140 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-Hydroxyethyl 5-norbornene-2-carboxylate t-butyl 5-norbornene-2-carboxylate 5-norbornene 2-carboxylic acid maleic anhydride | HCID 86593317 | — |
Reaction Steps
To tetrahydrofuran or toluene was added 0.5 to 0.95 mole of tert-butyl 5-norbornene-2-carboxylate, 0.05 to 0.8 mole of 2-hydroxyethyl 5-norbornene-2-carboxylate, 0.01 to 0.2 mole of 5-norbornene-2-carboxylic acid, 0.5 to 1 mole of maleic anhydride and 0.5 to 10 g of 2,2′-azobisisobutyronitrile (AIBN).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07150961B2 |
| Source dataset | uspto-grants-2006_12 |
| ORD ID | ord-3267418f7fcf4502b192575dc8bf3f18 |
| Source note | uspto-grants-2006_12 |