HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromothiazole → (2-Nitro-4-thiazol-2-yl-phenyl)-carbamic acid tert.-butyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromothiazole | HCID 76430 | — |
| Reactant | (2-Nitro-4-tributylstannanyl-phenyl)-carbamic acid tert.-butyl ester | HCID 23554337 | — |
| Product | (2-Nitro-4-thiazol-2-yl-phenyl)-carbamic acid tert.-butyl ester | HCID 69592824 | 26.2% |
Reaction Steps
Prepared from (2-nitro-4-tributylstannanyl-phenyl)-carbamic acid tert.-butyl ester (Example D2) (1.0 g, 1.9 mmol) and 2-bromothiazole (0.56 mL, 6.27 mmol) according to the general procedure E. Obtained as a yellow solid (160 mg). MS (EI) 321 (M+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07151098B2 |
| Source dataset | uspto-grants-2006_12 |
| ORD ID | ord-cb5c63288dcd47c4b09ae25678bc1549 |
| Source note | uspto-grants-2006_12 |