HCID 69592799, compound → HCID 69592773, compound

HRID 859322Notes

Reaction equation

HRID 859322 reaction equation
[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([O:20][CH3:21])[CH:15]=2)=[CH:10][C:9]=1[N+:22]([O-])=O)([CH3:4])([CH3:3])[CH3:2]>[Ni]>[C:1]([O:5][C:6](=[O:25])[NH:7][C:8]1[CH:13]=[CH:12][C:11]([C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([O:20][CH3:21])[CH:15]=2)=[CH:10][C:9]=1[NH2:22])([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 1

HCID 69592799HCID 69592799, compound

Product 1

HCID 69592773HCID 69592773, compound

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

Prepared from (3′-methoxy-3-nitro-biphenyl-4-yl)-carbamic acid tert.-butyl ester (Example B8) by catalytic hydrogenation with Raney-Ni according to the general procedure G (method a). Obtained as a white solid (165 mg).

Sources & evidence

ORD record
ord-b4861400ab424c0dbfef2e3af246af81
Source dataset
uspto-grants-2006_12
Patent number
US07151098B2

Reaction notes

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