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HRID859388

反应详情

EQUATION

反应方程式

HRID 859388 的结构方程式

REACTANTS

反应物

3
结构：[N-]=[N+]=Nc1cccc(C(=O)Cl)c1
HCID22224783

3-Azidobenzoyl chloride

C7H4ClN3O

结构：CC(C)(C)OC(=O)Nc1ccc(-c2ccccc2)cc1N
HCID57717454

未命名化合物

结构：CCOC(=O)CC(=O)c1cccc(N=[N+]=[N-])c1
HCID86587996

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)OC(=O)Nc1ccc(-c2ccccc2)cc1NC(=O)CC(=O)c1cccc(N=[N+]=[N-])c1
HCID86587995

未命名化合物

PROCEDURE

实验过程

Prepared (3-amino-biphenyl-4-yl)-carbamic acid tert.-butyl ester (Example G9) (569 mg, 2 mmol) and 3-(3-azido-phenyl)-3-oxo-propionic acid ethyl ester (700 mg, 3 mmol; prepared from 3-azido-benzoyl chloride (Bioorg. Chem 1986, 134) using the procedure described in Synthesis, 1993, 290, method A; MS (EI) 233 (M+)) according to the general procedure K. Obtained as an orange solid (367 mg).

WORKUP

后处理

  1. customdescribed in Synthesis, 1993, 290, method A