Acetic Acid → HCID 69398687, compound

Participants

Reaction Steps

To a suspension of D-glucose (36.0 g, 200.0 mmol) and Bn2NH (39.5 g, 200.0 mmol) in absolute EtOH (200 mL) was added AcOH (12.0 g, 200.0 mmol). Upon refluxing for 3 h, the reaction mixture was cooled and filtered with suction. The resulting filter cake was washed with EtOH to colorless and dried in a desiccator over calcium chloride to give 1-dibenzylamino-1-deoxy-D-fructose as a white solid (57.0 g, 79%).

Provenance & Evidence