HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 861516Generated: October 26, 2026
Nitric Acid → 6-Bromo-2-methoxy-1-nitronaphthalene
https://huagongshe.com/reaction/861516
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | 2-Bromo-6-methoxynaphthalene | HCID 78786 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 6-Bromo-2-methoxy-1-nitronaphthalene | HCID 22097187 | 90% |
Reaction Steps
10 ml of 98% strength nitric acid dissolved in 70 ml of acetic acid were added dropwise to 50 g (0.21 mol) of 6-bromo-2-methoxynaphthalene dissolved in 350 ml of acetic acid at room temperature. The mixture was heated to 50° C. and, after the product had crystallized, cooled. The precipitate was filtered off with suction to yield 53.1 g (90%) of the product. Melting point 156°-157° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05714489 |
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| Source dataset | uspto-grants-1998_02 |
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| ORD ID | ord-c67da7286795475fa5870991d3593d3c |
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| Source note | uspto-grants-1998_02 |
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