Potassium Nitrate → HCID 22097123, compound

HRID 861526Notes

Reaction equation

HRID 861526 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[N:8]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[C:7](=[O:18])[C:6](=[O:19])[NH:5]2.[N+:20]([O-])([O-:22])=[O:21].[K+]>S(=O)(=O)(O)O>[Cl:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][C:11]=1[N+:20]([O-:22])=[O:21])[N:8]([CH2:12][C:13]([O:15][CH2:16][CH3:17])=[O:14])[C:7](=[O:18])[C:6](=[O:19])[NH:5]2

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 22097085HCID 22097085, compound

Product 1

HCID 22097123HCID 22097123, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Procedure

69.8 g (0.25 mol) of 6-chloro-1-(ethoxycarbonylmethyl)-2,3(1H,4H)-quinoxalinedione were dissolved in 625 ml of concentrated sulfuric acid and, at 0° C., 25 g (0.25 mol) of potassium nitrate were added a little at a time. The cooling was then removed, and the mixture was stirred until reaction was complete. The mixture was poured into ice-water, and the precipitate was filtered off with suction to yield 77.8 g (95%) of the product.

Workup

  1. customThe cooling was then removed
  2. additionThe mixture was poured into ice-water
  3. filtrationthe precipitate was filtered off with suction

Sources & evidence

ORD record
ord-15aeaa931ea348d6ab4ef0a36ae9cf92
Source dataset
uspto-grants-1998_02
Patent number
US05714489

Reaction notes

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