HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloroform → 3,6-Dioxatricyclo[5.4.0.0,2,4]undeca-1(11),7,9-triene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloroform | HCID 6212 | — |
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | Benzopyran | HCID 9211 | — |
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 3,6-Dioxatricyclo[5.4.0.0,2,4]undeca-1(11),7,9-triene | HCID 13149033 | — |
Reaction Steps
The compound 5 is oxidized with an oxidizing agent such as m-chloroperbenzoic acid and peracetic acid in a solvent such as chloroform, methylene chloride and ether, under cooling to room temperature to give 3,4-epoxychroman (compound 6 wherein R1, R2 and R3 are as defined above).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05719155 |
| Source dataset | uspto-grants-1998_02 |
| ORD ID | ord-90bec408a66c447abc6e93e4705880ed |
| Source note | uspto-grants-1998_02 |