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HRID863326

反应详情

EQUATION

反应方程式

HRID 863326 的结构方程式

REACTANTS

反应物

4
结构：COC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]
HCID2723798

(Methoxymethyl)(triphenyl)phosphanium chloride

C20H20ClOP

结构：C[Si](C)(C)[N-][Si](C)(C)C.[K+]
HCID3251421

Potassium bis(trimethylsilyl)amide

C6H18KNSi2

结构：O=CC1CN(C(=O)OCc2ccccc2)c2ccccc2O1
HCID19697651

未命名化合物

结构：C=CCOCC1Cc2ccccc2N(C(=O)CC(C)(C)C[C@H](NC(=O)OC(C)(C)C)[C@@H](O)C[C@@H](C)C(=O)NCCCC)C1
HCID131720529

未命名化合物

PRODUCTS

生成物

1
结构：COC=CC1CN(C(=O)OCc2ccccc2)c2ccccc2O1
HCID73649459

未命名化合物

PROCEDURE

实验过程

The title compound is prepared analogously to the process described in Example 138b) starting from 1.25 g of N-benzyloxycarbonyl-2(R,S)-formyl-3,4-dihydro-2H-1,4-benzoxazine (Example 107), 7.2 g of methoxymethyl-triphenylphosphonium chloride and 1.57 g of potassium bis(trimethylsilyl)amide: Rf (A)=0.49 und 0.54.