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HRID863331

反应详情

EQUATION

反应方程式

HRID 863331 的结构方程式

REACTANTS

反应物

3
结构：CC=CC[C@H](C[C@H](O)[C@H](CC(C)(C)CCO[Si](c1ccccc1)(c1ccccc1)C(C)(C)C)NC(=O)OC(C)(C)C)C(=O)NCCCC
HCID57261199

未命名化合物

结构：CC=CC[C@@H]1C[C@@H]([C@H](CC(C)(C)CCO[Si](c2ccccc2)(c2ccccc2)C(C)(C)C)NC(=O)OC(C)(C)C)OC1=O
HCID67625916

未命名化合物

结构：C=C(C)C[C@H](C[C@@H]1OC(C)(C=C=O)N(OC(C)(C)C)[C@H]1CC(C)(C)CCOCc1ccccc1)C(=O)NCCCC
HCID86752115

未命名化合物

PRODUCTS

生成物

1
结构：CC=CC[C@H](C[C@@H]1OC(C)(C)N(C(=O)OC(C)(C)C)[C@H]1CC(C)(C)CCO[Si](c1ccccc1)(c1ccccc1)C(C)(C)C)C(=O)NCCCC
HCID131720537

未命名化合物

PROCEDURE

实验过程

Starting from 472 mg of 3(R)-but-2-enyl-5(S)-[5-tert-butyl-diphenylsilyloxy-1(S)-tert-butoxycarbonylamino-3,3-dimethyl-pentyl]-2-oxo-tetrahydrofuran via 2(R)-but-2-enyl-9-tert-butyldiphenylsilyloxy-5(S)-tert-butoxycarbonylamino-4(S)-hydroxy-7,7-dimethyl-nonanoic acid (N-butyl)amide (Rf (A)=0.64; FAB-MS: (M+H)+ =681) analogously to Examples 74b and 74c): Rf (B)=0.71; FAB-MS: (M+H)+ =721.