Dibenzylphosphate → Silver(1+) dibenzyl phosphate

HRID 864952Notes

Reaction equation

HRID 864952 reaction equation
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].C(=O)([O-])[O-].[Ag+2:24]>C(#N)C.O.[Al]>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:24]

Participants

6

Reactant 2

HCID 4193600DibenzylphosphateHCID 178418647HCID 178418647, compound

Product 1

HCID 13248164Silver(1+) dibenzyl phosphate

Reagents, catalysts & solvents 3

HCID 962WaterSolventHCID 6342AcetonitrileSolventHCID 5359268AluminumSolvent

Procedure

Dibenzyl phosphate (10 mmole, 2.78 g) is dissolved in a mixture of acetonitrile (20 ml) and water (10 ml). Silver carbonate (10 mmole, 2.76 g) is added, and the mixture is stirred at room temperature in the dark (wrapped in aluminum foil) for 2 hours. Excess of silver carbonate is removed by filtration. The solution is evaporated to dryness, and dried over P2O5 in the dark to constant weight (2 days). Yield of silver dibenzoyl phosphate is 3.61 g.

Workup

  1. customExcess of silver carbonate is removed by filtration
  2. customThe solution is evaporated to dryness
  3. dry with materialdried over P2O5 in the dark to constant weight (2 days)

Sources & evidence

ORD record
ord-39b55e4f9ff449309a8e74ffe687fd81
Source dataset
uspto-grants-1996_10
Patent number
US05565439

Reaction notes

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