HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → 3-(Bromomethyl)benzene-1-sulfonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 3-Methylbenzenesulphonyl chloride | HCID 2734595 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 3-(Bromomethyl)benzene-1-sulfonyl chloride | HCID 23447389 | — |
Reaction Steps
N-Bromosuccinimide (6.27 g, 0.035 mole), m-toluenesulfonyl chloride (6.72 g, 0.035 mole), and benzoyl peroxide (0.67 g, 0.0019 mole) were combined in CCl4 (40 mL) and heated at reflux 2 h. The reaction mixture was filtered and washed with CCl4. The filtrate was concentrated to give m-bromomethylbenzenesulfonyl chloride, 9.74 g, as a viscous yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05569659 |
| Source dataset | uspto-grants-1996_10 |
| ORD ID | ord-00c80fcad393444eb335e6d9d03444a8 |
| Source note | uspto-grants-1996_10 |