1-(Dimethylamino)pent-1-en-3-one → HCID 21357338, compound

HRID 866700Notes

Reaction equation

HRID 866700 reaction equation
CN(C)[CH:3]=[CH:4][C:5](=[O:11])[CH2:6][CH2:7][CH2:8][CH2:9]C.CN(C)[CH:15]=[CH:16]C(=O)CC.CN(C)[CH:24]=[CH:25][C:26](=[O:30])[CH2:27][CH2:28][CH3:29].CN(C)[CH:34]=[CH:35][C:36](=[O:41])[CH2:37][CH2:38][CH2:39][CH3:40].CN(C)[CH:45]=[CH:46][C:47](=[O:54])[CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53].CN(C)[CH:58]=[CH:59]C(=O)CCCCCCC>>[CH2:9]=[CH:8][CH:7]=[CH:6][C:5](=[O:11])[CH2:4][CH3:3].[CH2:15]=[CH:16][CH:24]=[CH:25][C:26](=[O:30])[CH2:27][CH2:28][CH3:29].[CH2:45]=[CH:46][CH:34]=[CH:35][C:36](=[O:41])[CH2:37][CH2:38][CH2:39][CH3:40].[CH2:58]=[CH:59][CH:45]=[CH:46][C:47](=[O:54])[CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53]

Participants

10

Reactant 6

HCID 217684671-(Dimethylamino)pent-1-en-3-oneHCID 537212411-(Dimethylamino)non-1-en-3-oneHCID 54247135HCID 54247135, compoundHCID 54273728HCID 54273728, compoundHCID 54424515HCID 54424515, compoundHCID 545630821-(Dimethylamino)-1-octen-3-one

Product 4

HCID 21357338HCID 21357338, compoundHCID 53783551HCID 53783551, compoundHCID 54218293Nona-1,3-dien-5-oneHCID 54359857HCID 54359857, compound

Procedure

In the same manner but replacing 1-(dimethylamino)-1-octen-3-one with an equivalent amount of 1-(dimethylamino)-1-penten-3-one, 1-(dimethylamino)-1-hexen-3-one, 1-(dimethylamino)-1-hepten-3-one, 1-(dimethylamino)-1-nonen-3-one or 1-(dimethylamino)-1-decen-3-one, then 1,3-heptadien-5-one, 1,3-octadien-5-one, 1,3-nonadien-5-one, 1,3-undecadien-5-one and 1,3-dodecadien-5- are obtained, respectively.

Sources & evidence

ORD record
ord-abc1e6da28a0467bafa6334e6f8efd2a
Source dataset
uspto-grants-1978_07
Patent number
US04100343

Reaction notes

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