Bicyclo(2.2.2)oct-2-ene → HCID 20319819, compound

HRID 866709Notes

Reaction equation

HRID 866709 reaction equation
[CH:1]12[CH2:13][CH2:12][CH:4]([CH:5]([CH2:7][CH2:8][C:9]([OH:11])=[O:10])[CH2:6]1)[CH:3]=[CH:2]2.[CH2:14]=C1CC2CCC1C=C2.CC1C(C)C2CCC1CC2CC(O)=O.CC1C(C)C2CCC1C=C2.C12CCC(CC1)CC2CC(O)=O.C12CCC(CC1)C=C2.C(C12C(CC)(CC)CC(CC1)CC2CCC(O)=O)C.C=C1CC2CC(CC)(CC)C1(CC)CC2.C12CCC(C=C1)CC2CC(O)=O.C12CCC(C=C1)C=C2.C(C1C(C(C)C)C2CCC1CC2CC(O)=O)(C)C.C(C1C(C(C)C)C2CCC1C=C2)(C)C>>[CH3:14][CH:6]1[CH:1]2[CH2:13][CH2:12][CH:4]([CH2:3][CH2:2]2)[CH:5]1[CH2:7][CH2:8][C:9]([OH:11])=[O:10]

Participants

13

Reactant 12

HCID 13608Bicyclo(2.2.2)oct-2-eneHCID 136325Bicyclo(2.2.2)octa-2,5-dieneHCID 1405255-Methylidenebicyclo[2.2.2]oct-2-eneHCID 12935337HCID 12935337, compoundHCID 18939219HCID 18939219, compoundHCID 20319795HCID 20319795, compoundHCID 20319801HCID 20319801, compoundHCID 20319803HCID 20319803, compoundHCID 20319818HCID 20319818, compoundHCID 203198201539768-12-1HCID 20319823HCID 20319823, compoundHCID 20319833HCID 20319833, compound

Product 1

HCID 20319819HCID 20319819, compound

Procedure

Similarly in an analogous manner 3-(bicyclo[2.2.2]oct-2-en-5-yl)propionic acid; is prepared from 5-methylenebicyclo[2.2.2]oct-2-ene; 5,6-dimethylbicyclo[2.2.2]oct-2-ylacetic acid from 5,6-dimethylbicyclo[2.2.2]oct-2-ene; bicyclo[2.2.2]oct-2-ylacetic acid from bicyclo[2.2.2]oct-2-ene; 3-(1,7,7-triethylbicyclo[2.2.2]oct-2-yl)propionic acid from 2-methylene-1,7,7-triethylbicyclo[2.2.2]octane; bicyclo[2.2.2]oct-5-en-2-ylacetic acid from bicyclo[2.2.2]octa-2,5-diene and 5,6-diisopropylbicyclo[2.2.2]oct-2-ylacetic acid from 5,6-diisopropylbicyclo[2.2.2]oct-2-ene.

Sources & evidence

ORD record
ord-c4f53d3e23a548cfa6a86fd532feea53
Source dataset
uspto-grants-1978_07
Patent number
US04100193

Reaction notes

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