Hydrazine hydrate (1:1) → HCID 54042176, compound

Participants

Reaction Steps

The mixture of 0.3g of 9-cyano-2-fluoro-10,11-dihydrodibenzo[b,f]thiepin-11-one, 0.3g of 100% hydrazine hydrate and 10ml of ethanol was heated under reflux on water-bath for 5 hours. The reaction mixture was concentrated to 5ml to separate crystals on cooling, which was collected by filtration. Recrystallization from ethanol afforded 0.3g of 9-cyano-2-fluoro-10,11-dihydrodibenzo[b,f]thiepin-11-one hydrazone as pale yellow needles having a melting point of 220°-222° C.

Provenance & Evidence