HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl chloride → 1-(3,3-Dimethylcyclohexyl)ethanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-(3,3-Dimethylcyclohexyl)ethanone | HCID 91388 | — |
| Product | 1-(3,3-Dimethylcyclohexyl)-pent-4-en-1-one | HCID 6453423 | — |
| Product | 1-Acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane | HCID 53724607 | — |
Reaction Steps
A mixture of 1-acetyl-3,3-dimethylcyclohexane (156 grams, 1 mole), sodium hydroxide (60 grams, 1.5 moles), allyl chloride (114 grams, 1.5 moles) and triethylamine (10 grams) is stirred and heated at 80°-84° C. for 12 hours. The reaction mass is cooled to room temperature. Water is added with stirring, and the aqueous layer is discarded. The organic layer is distilled to afford 119 grams of 1-acetyl-3,3-dimethylcyclohexane, 31 grams of 1-acetyl-3,3-dimethyl-1-(2-pentenyl) cyclohexane, and 5 grams of 3,3-dimethyl-1-(4-pentenoyl) cyclohexane.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04102928 |
| Source dataset | uspto-grants-1978_07 |
| ORD ID | ord-eea4779a8076450b860971bd9ec322b9 |
| Source note | uspto-grants-1978_07 |