Tetramethylammonium isopropylcarbonate → Methanaminium, N,N,N-trimethyl-, carbonate (1:1)

HRID 867851Notes

Reaction equation

HRID 867851 reaction equation
C([O:4][C:5](=[O:7])[O-:6])(C)C.[CH3:8][N+:9]([CH3:12])([CH3:11])[CH3:10]>O>[C:5](=[O:4])([O-:7])[OH:6].[CH3:8][N+:9]([CH3:12])([CH3:11])[CH3:10]

Participants

3

Reactant 1

HCID 21288598Tetramethylammonium isopropylcarbonate

Product 1

HCID 10197721Methanaminium, N,N,N-trimethyl-, carbonate (1:1)

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

88.5 g of tetramethylammonium isopropylcarbonate and 45.0 g of water were introduced in the same reactor as used in Preparation Example 1 and heated with stirring. After the temperature reached 120° C., the reaction was continued for 3 hours at 120° C. Tetramethylammonium hydrogencarbonate was obtained in a yield of 95.0 mol %.

Workup

  1. customas used in Preparation Example 1
  2. temperatureheated
  3. customreached 120° C.

Sources & evidence

ORD record
ord-7a20e710abc944ee8b6e158cc9b9eb4d
Source dataset
uspto-grants-1988_10
Patent number
US04776929

Reaction notes

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