HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chlorotrimethylsilane → HCID 14278942, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1-[(t-Butoxycarbonyl)amino]-2-imidazolidinone | HCID 14278941 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | HCID 14278942 | HCID 14278942 | 91.1% |
Reaction Steps
While cooling 10.55 g (97.1 mmol) of chlorotrimethylsilane was dropped into a solution of 19.55 g (97.1 mmol) of (2-oxo-1-imidazolidinyl)carbamic acid, 1,1-dimethylethyl ester and 9.83 g (97.1 mmol) of triethylamine in 900 ml of absolute ethyl acetate. After stirring overnight, the salt was filtered off and the filtrate evaporated in vacuo to yield 24.18 g of the title compound; melting point 132.1° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04777252 |
| Source dataset | uspto-grants-1988_10 |
| ORD ID | ord-2c12d828e29b46a1b1c02510217591c5 |
| Source note | uspto-grants-1988_10 |