Potassium thiocyanate → HCID 54142305, compound

HRID 868695Notes

Reaction equation

HRID 868695 reaction equation
[C:1]([S-:3])#[N:2].[K+].[CH2:5]([S:11][CH2:12][CH2:13][CH2:14]Cl)[CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]>>[CH2:5]([S:11][CH2:12][CH2:13][CH2:14][N:2]=[C:1]=[S:3])[CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

3

Reactant 2

HCID 516872Potassium thiocyanateHCID 85582446HCID 85582446, compound

Product 1

HCID 54142305HCID 54142305, compound

Procedure

n-C6H13SCH2CH2CH2Cl is added to a solution of KSCN in refluxing N,N-dimethylformamide at about 155° C. in an amount sufficient to provide a n-C6H13SCH2CH2Cl:KSCN molar ratio of about 1:1. Upon completion of the addition of n-C6H13SCH2CH2CH2Cl, the reaction mixture is refluxed an additional 0.5 hours. The amount of n-C6H13SCH2CH2CH2NCS formed was measured by gas chromatography/mass spectrometry.

Workup

  1. temperaturethe reaction mixture is refluxed an additional 0.5 hours
  2. customThe amount of n-C6H13SCH2CH2CH2NCS formed

Sources & evidence

ORD record
ord-6bf1c7e5d4fa4202adcd3cefc385c0ff
Source dataset
uspto-grants-1988_10
Patent number
US04780557

Reaction notes

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