Bromine → HCID 86658906, compound

HRID 868764Notes

Reaction equation

HRID 868764 reaction equation
[CH:1]1[CH:19]=[CH:18][C:15]2=[C:16]3[C:17]4[C:9](=[CH:10][CH:11]=[CH:12][C:13]=4[S:14]2)[C:8]2[C:3](=[CH:4][CH:5]=[CH:6][CH:7]=2)[C:2]=13.[Br:20]Br>C(Cl)(Cl)Cl>[Br:20][C:10]1[CH:11]=[CH:12][C:13]2[S:14][C:15]3[CH:18]=[CH:19][CH:1]=[C:2]4[C:16]=3[C:17]=2[C:9]=1[C:8]1[C:3]4=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 24408BromineHCID 50219Triphenyleno(4,5-bcd)thiophene

Product 1

HCID 86658906HCID 86658906, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

Triphenyleno[1,12-bcd]thiophene (1.5 g, 5.8 mmol) was dissolved in 100 mL of chloroform. Br2 was slowly added into the reaction solution. After the reaction was stirred at room temperature for 3 days, the mixture was filtered through a Celite plug and washed by CH2Cl2. The combined filtrate was concentrated to get 2.2 g of 7-bromotriphenyleno[1,12-bcd]thiophene which was used for next step without further purification.

Workup

  1. filtrationthe mixture was filtered through a Celite plug
  2. washwashed by CH2Cl2
  3. concentrationThe combined filtrate was concentrated

Sources & evidence

ORD record
ord-75c6ff9c6b0a4aaca011b1a8b70951b0
Source dataset
uspto-grants-2015_03
Patent number
US08968887B2

Reaction notes

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