Ammonia → HCID 131730347, compound

HRID 870072Notes

Reaction equation

HRID 870072 reaction equation
[C:1]([C:5]([C:8]([O:11][C:12]([C:15]([C:18]([C:21]([OH:23])=[O:22])([F:20])[F:19])(F)[F:16])([F:14])[F:13])(F)[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].C(C(C(OC(C(C(C(O)=O)(F)F)F)(F)F)F)(F)F)(F)(F)F.[NH3:45].C(C(C(OC(C(C(C([O-])=O)(F)F)(F)F)(F)F)(F)F)(F)F)(F)(F)F.[NH4+]>>[C:1]([C:5]([CH:8]([O:11][C:12]([CH:15]([C:18]([C:21]([O-:23])=[O:22])([F:19])[F:20])[F:16])([F:13])[F:14])[F:9])([F:7])[F:6])([F:4])([F:3])[F:2].[NH4+:45]

Participants

5

Reactant 4

HCID 222AmmoniaHCID 87161156HCID 87161156, compoundHCID 87161157Perfluoro-4-propoxybutanoic acidHCID 131730348HCID 131730348, compound

Product 1

HCID 131730347HCID 131730347, compound

Procedure

NMR analysis clarified that the fraction 1 was CF3CF2CF2OCF2CF2CF2COOH and the fraction 2 was CF3CF2CHFOCF2CHFCF2COOH. These were neutralized with ammonia so that CF3CF2CF2OCF2CF2CF2COONH4 and CF3CF2CHFOCF2CHFCF2COONH4 were obtained.

Sources & evidence

ORD record
ord-0c14634372dc4d308f2d551925073c74
Source dataset
uspto-grants-2015_03
Patent number
US08969437B2

Reaction notes

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