HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodoethane → 9-Ethyl-9H-fluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodoethane | HCID 6340 | — |
| Reactant | Fluorene | HCID 6853 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | 9-Ethyl-9H-fluorene | HCID 16801 | 97.5% |
Reaction Steps
Fluorene (5.0 g, 30.1 mmol), n-BuLi (16 ml, 40 mmol, 2.5 M in hexane), RX=iodoethane (7.04 g, 45.1 mmol). 41 was isolated as yellow oil (5.7 g, 97%). Analytical data were identical to those in the literature (K. D. Bartle, P. M. G. Bavin, D. W. Jones, R. L'Amie, Tetrahedron 1970, 26, 911).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08969624B2 |
| Source dataset | uspto-grants-2015_03 |
| ORD ID | ord-254fceaf47f8491e919b2fad3dd7405e |
| Source note | uspto-grants-2015_03 |