HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromohexadecane → HCID 58947033, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromohexadecane | HCID 8213 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 1,3-Benzenedicarboxylic acid, 5-hydroxy-, 1,3-dimethyl ester | HCID 83065 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | HCID 58947033 | HCID 58947033 | 86.5% |
Reaction Steps
The product was generated using general protocol D using dimethyl-5-hydroxyisophthalate (3.920 g, 18.7 mmol), 1-bromohexadecane (5.18 g, 17.0 mmol), K2CO3 (9.37 g, 67.8 mmol), CH3CN (100 mL) yielded 6.30 g (86.5%) of a white solid. 1H NMR (CDCl3, 600 MHz) δ: 8.26 (t, 3J=1.4 Hz, 1H, Ar—H), 7.74 (d, 3J=1.5 Hz, 2H, Ar—H), 4.03 (t, 3J=6.5 Hz, 2H, O—CH2), 3.94 (s, 6H, COO—CH3), 1.80 (p, 3J=7.3 Hz, 2H, OCH2CH2), 1.46 (p, 3J=7.6 Hz, 2H, OCH2CH2CH2), 1.26 (m, 24H), 0.88 (t, 3J=6.8, 3H, CH2—CH3.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08980925B2 |
| Source dataset | uspto-grants-2015_03 |
| ORD ID | ord-49312266d8964a1286455b8a0a5a9a27 |
| Source note | uspto-grants-2015_03 |