HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Iodide → 1-Allyl-4-methyl-1,4-azaphosphinane 4-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Iodide | HCID 5238 | — |
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | Cesium carbonate | HCID 10796 | — |
| Reactant | 4-Methyl-1,4lambda5-azaphosphinan-4-one hydrochloride | HCID 66833053 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 1-Allyl-4-methyl-1,4-azaphosphinane 4-oxide | HCID 68153111 | — |
Reaction Steps
To a mixture of 4-methyl-1,4-azaphosphinane 4-oxide hydrogen chloride salt (1.69 g), sodium iodide (150 mg) and Cs2CO3 (7.15 g) in acetone (50 mL) was added allyl chloride dropwise. The mixture was stirred at room temperature overnight, filtered and concentrated to provide the desired product as white solid (1.45 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08987284B2 |
| Source dataset | uspto-grants-2015_03 |
| ORD ID | ord-9db6e368a018448f9734c2e9e6e3a025 |
| Source note | uspto-grants-2015_03 |